Chapter 3: Priority Concerns Related to Chemical Production, Import, Export and Use

3.1Priority Concerns Related to Chemical Production, Import, Export and Use

3.1Priority Concerns Related to Chemical Production, Import, Export and Use

Table 3.A : Description of Problem Areas

Nature of Problem

City/Region

Brief Description of Problem

Chemical (s) / Pollutant (s)

Air pollution Thailand

Air pollution mainly comes from vehicles, constructions and industries. Vehicles and constructions cause air pollution in large urban centres, while industrial air pollution is a locality specific problem found in both urban and rural areas.

Total Suspended Particulate Matter (TSP), PM10, carbon monoxide,nitrogen dioxide, sulphur dioxide, ozone.
  Bangkok/ Thailand

It was reported by the Pollution Control Department in 1995 that curbside air quality in many areas of Bangkok was the serious problem, particularly with regard to Total Suspended Particulate Matter (dust). Some pollutants such as carbon monoxide at 8 hours, nitrogen dioxide and ozone were found to be higher concentration than the standard levels.

Total Suspended Particulate Matter (TSP), PM10 , carbon monoxide, NO2 and ozone.
  Mae Moh, Lampang Province/ Thailand

In 1992, the combustion of lignite to generate electric power at Mae Moh Power Plant, Lampang Province, was the major cause of air pollution in the surrounding area.

Sulphur dioxide
Pollution of Inland Waterways Thailand

Natural water resources along with rivers and canals in various agricultural areas all over country were investigated for pesticides residues by the Division of Agricultural Toxic Substances, Department of Agriculture, Ministry of Agriculture and Cooperatives. The Contamination of pesticides in water and sediments, in general, was rather low, especially, water resources for domestic consumption like ponds and reservoirs which have no connection way to agricultural plantations. However, the water resources in certain agricultural areas e.g. in orchid and ornamental plantations, were contaminated with organophosphorous and carbamate insecticides.

Insecticides:

- Organophosphate

- Organonochlorine

- Carbamate

Herbicides:

- Chlorophenoxy acetic acid

- Quaternary ammonium compounds

- Triazine

Fungicides:

- Copper compounds

- Phathalimides

Marine Pollution Thailand

Marine water quality in coastal areas is still in good condition except at the tourist and industrial areas. This is because of discharge of waste water from communities and factories, aquaculture farms, ranch and agricultural land that are contaminated with organic matters, fertilizer, pesticides and antibiotics. The direct waste water discharge and the transport of pollution from river is a factor that accelerates water quality degradation.

Heavy metals (mercury, lead, cadmium, chromium, copper, nickel, manganese, zinc), total organochlorine pesticides (DDT, alpha-BHC, dieldrin, aldrin, endrin, heptachlor & heptachlor epoxide)
Groundwater Pollution Central and Western Thailand

The study on ground-water quality in some provinces of the central and western Thailand (Suphanburi, Saraburi, Ratchaburi, Kanchanaburi, Uthai Thani,Phetchaburi and Lopburi) was conducted by the Pollution Control Department in 1994. It was reported that pesticides residues and heavy metals found in groundwater samples were mostly below the standard levels of WHO.

Chlorinated compounds (heptachlor, dieldrin, aldrin, BHC, DDT, endosulfan ) atrazine, carbofuran, 2,4 ?D, heavy metals ( mercury, cadmium, lead, arsenic )
Soil Contamination Tak Province/ Thailand

There was an evidence of soil contamination caused by leakage of heavy metals from smelting process in Zinc Refinery Plant. This contamination affected the soil in paddy fields surrounded the refinery plant with high level of heavy metals particularly zinc and cadmium.

Heavy metals (cadmium, zinc, lead, manganese)
  Northern, Eastern, North-eastern, Central, Southern

A monitoring program of pesticide residues in soil collected from agricultural areas of Thailand had been conducted since 1973. The major pesticide residues found during the year 1973-1977, were organochlorine insecticides. In 1973, the maximum amount of residues found was total DDT 27.57 ppm which gradually declined to 0.336 ppm in 1977, and 0.234 ppm in 1988. The organophosphorous insecticide residues were also found in 1973, 1974 and 1988 but the amount was at low levels.

Organochlorine:

- alpha- BHC - lindane

- heptachlor & epoxide

- aldrin & dieldrin

- endrin - total DDT

Organophosphates:

- diazinon - dimethoate

- malathion , parathion-methyl

Carbamate:- carbofuran

Shallow-well water Pollution Thailand

Shallow-wells in 4 districts of Rayong Province were investigated in1993 by the Division of Agricultural Toxic Substances, Department of Agriculture, Ministry of Agriculture and Cooperatives. 160 water samples were collected for analysis of organochlorine-organophosphorus insecticides, fungicide(carbendazim) and herbicide(paraquat). The result showed that 67% of samples were contaminated with dieldrin, DDT-derivatives, dicofol, endosulfan, beta-BHC and parathion-methyl. The quantity of residues found was lower than the tolerance level. However, neither residues of fungicide nor herbicide were detected.

Organochlorine insecticides:

- dieldrin < 0.01-0.14 ppb

- DDT derivatives < 0.01-0.07 ppb

- dicofol 0.01-0.02 ppb

- endosulfan 0.02-0.05 ppb

- beta-BHC < 0.01-0.10 ppb

Organophosphoropus insecticides:

- parathion-methyl < 0.01 ppb

 

 

Unknown Chemical Imports.

N.A.

N.A.

N.A.

Hazardous Waste Treatment/Disposal Thailand

The amount of hazardous waste generated nationwide in 1994 was about 1.35 million tons, of which 73 percent was from the industrial sector. The remainder was generated within the community from sources such as hospitals, the commercial sector, shipping services, sea port activities etc.

To dispose the amount of hazardous waste mentioned above, the Department of Industrial Works therefore set up the industrial waste disposal center at Samae Dum, Bangkok. This center can serve hazardous waste from approximately 460 medium and small scale factories. However, large scale factories are able to treat and dispose their industrial waste. In addition, the other 4 waste disposal centers are planned to be set up in other industrial areas, namely Ratchaburi, Chon Buri, Saraburi and Rayong Province.

Hazardous waste
  Bangkok Metropolitan Area/Thailand

In 1995, the amount of 11 tons of infectious waste was collected daily from 592 hospitals in Bangkok Metropolitan Area.

Infectious waste
Hazardous Waste Treatment/Disposal

(cont.)

Kanchanaburi Province/ Thailand

One thousand and two hundred drums of toxic wastes caused by fire accident of chemical warehouses at Klong Toey Port, Bangkok in 1991 were treated properly by secure landfill in Kanchanaburi Province.

Carbon black, toluene, thinner, soda ash, corrosive substances, cyanide compounds, fertilizers, methyl bromide, paraformaldehyde, insecticides, DDT
Occupational Health : Agriculture Region

The statistics report of sickness and death from pesticides, by the Epidemiology Division, Ministry of Public Health, in 1995, indicated 3,354 sickness cases, and 20 deaths. When compared to the statistics in 1994 with 3,165 sickness cases and 41 deaths.

Pesticides
Occupational Health : Industrial Region

Health impact from hazardous chemicals used in industry such as lead, manganese, mercury, arsenic and toxicity from petroleum products and volatile gases by the Epidemiology Division, Ministry of Public Health, in 1995, indicated that 159 people were affected.

Lead, manganese,mercury arsenic,petroleum products and volatile gases
Chemical Accidents: Industrial Region

There were reports of accidents from industries, which resulted in more people suffering from toxicity of hazardous chemicals such as, a leakage of chlorine gas in a clinical gloves manufacturing plant in Samut Prakarn in October 1995, resulting in 5 injuries. Also there was an explosion of ammonia gas in the refrigerator room of a seafood export factory in Samut Prakarn, resulting in 3 injuries.

Chlorine gas, ammonia gas
Chemical Accidents: Transport Bangkok/ Thailand

There was an explosion caused by the LPG truck accident at New Petchburi Road Bangkok in 1990. Many people were injured by this accident and 91 of them were dead. Moreover, approximately 30 residential buildings and 43 cars were completely destroyed in the massive blast.

LPG (Liquid Petroleum Gas)
  Phangnga Province/ Thailand

There was an explosion caused by the dynamite truck accident at Phangnga Province in 1991. In this case, 207 people were dead and more were injured.

TNT (trinitroluene)
  Samut Prakan Province/ Thailand

The amount of vinyl chloride was leaked from the highly volatile tanks on a ship and polluted to Chao Phraya River at Samut Prakarn Province in 1992.

Vinyl chloride
Storage / Disposal of Obsolete Chemical Bangkok/ Thailand

The fire accident of chemical warehouses was occured at Klong Toey Port , Bangkok in 1991. This accident killed 6 people, injured 16 people and destroyed 642 residential buildings.

Methyl bromide, oxidizing agents, pesticides and carbon black.
  Rayong Province/ Thailand

About 1,000 tons of industrial toxic waste containers from the petrochemical industrial plant were dumped near the industrial estate at Rayong Province.

Acrylonitrile - Butadiene - Styrene (ABS), benzene
Persistent Organic Pollutants Thailand The importation of POPs pesticides was first reported in 1971 when toxaphene and DDT were the biggest volumes of 62 and 1,968 metric tons respectively. Dieldrin, aldrin, endrin, chlordane and heptachlor were less volumes of 8, 6, 0.8, 3 and 1 metric tons respectively. Importation of such POPs pesticides has been increased years after years. They were both increased and decreased in volumes each year but most of them were increased until they were banned in specified years for the reasons of human health and environment impacts. Only chlordane has been used longer than all others till 1996. However, importation of almost all specified POPs chemicals has been prohibited for all uses by final governmental regulatory action. For PCBs, it has been used in small amount as industrial fluid for the hydraulic system and gas turbine, as lubricating oil and as plasticizer. The imported volumes or when it was first imported for these purposes have never been recorded. The other purposes and relatively in big volume is as a dielectric fluid for electric capacitor and transformer known as askarel. No reports have been made on when it was first imported either. It was recognized as a major existing hazardous waste of concern in the electric utility industry as PCBs contaminated equipment. However, importation of the electricity capacitors and transformers containing PCBs was totally banned in 1975. aldrin, chlordane, DDT, dieldrin, endrin, heptachlor, toxaphene, PCBs
Chemical Residues in Food

Nationwide

Monitoring of chemical contamination in food stuff has been carried out routinely by the Ministry of Public Health and Ministry of Agriculture & Co-operatives. The results of the study by Department of Medical Sciences during of period of 1987 ? 1991

( B.E. 2530 ? 2534 ) showed that :

1. Seafood was contaminated with more mercury and cadmium than any other foods. Moreover, street foods were contaminated with lead from automobile exhaust.

2. Pesticide residues were more frequently detected in fruits with edible peel

( grape, guava, water rose apple, common jujube, and strawberry ) than in vegetables. Organophosphate residues were frequently found. However, most of them were below maximum residue limits ( MRLs).

3. Trichlorfon was pesticide residue of concern in dried / salted fish (typical Thai food).

4. Certain veterinary drug residues were detected in meat / edible offal of cattle, pigs and poultry, mostly below the limits.

5. Some chemicals, such as borax, formalin, sodium dithiosulfite, were misused in food products.

Heavy Metals:

- Cadmium

- Mercury

- Lead

Pesticide Residues:

- Organophosphates (mostly)

Veterinary Drug Residues:

- Sulfa drugs in animal products

- Penicillin in milk.

Other chemicals:

- Borax, Formalin, Sodium dithiosulfite

Drinking Water Contamination Nakhon Srithammarat/ Southern Thailand

Drinking water from underground reservoirs and artesian wells in Ron-pee-boon District, Nakhon Srithammarat Province, has been contaminated with arsenic (above the limit), caused by tin mining.

Arsenic
Public Health Provinces on the boundaries between Thailand and neighbouring countries, esp. Myanmar.

Located in tropical zone, Thailand has had high risk of mosquito-borne diseases, especially Malaria. In 1994-1995, the annual malaria incidences for the population of 1,000 were 2.01 and 1.55 respectively. Although the morbidity rate for the disease has been reduced, the use of chemicals to control vector mosquitoes still proves necessary in high risk areas. The problem of concern is the use of DDT since this highly toxic chemical is resistant to breakdown, persistent in the environment and easily bioaccumulated in organisms. However, there has been increasing use of alternative pesticides and biological / environmental control measures in lieu of DDT over the years.

Chemicals used to control vector mosquitoes :

- DDT

- Deltamethrin

- Lambda-cyhalothrin

- Fenitrothion

- Temephos ( Abateā )

- Permethrin

 

Chemical Poisoning / Suicides Local

In 1995, the total prevalence of suicidal reported cases using toxic chemicals was 7.92 for the population of 100,000. Chemicals involved in these suicidal cases were mainly pesticides (30.79%) and herbicides (11.65%). The northern region of Thailand had the highest rate of poisoning.

Pesticides

Herbicides

Sedatives and hypnotics

Rodenticides

 

Table 3.B: Priority Concerns Related to Chemicals

Nature of Problem

Scale of Problem1

Level of Concern2

Ability to Control Problem2

Availability of Statistical Data 3

Specific Chemicals Creating Concerns

Priority Ranking4

Air Pollution

(vehicles)

local

high

medium

sufficient

Total Suspended Particulate Matter (TSP), PM10, carbon monoxide, nitrogen dioxide, sulphur dioxide, ozone.

1

Air Pollution

(construction)

local

high

medium

sufficient

TSP, PM10

1

Air Pollution

(industry)

local

medium

medium

insufficient

TSP, sulphur dioxide, nitrogen dioxide

2

Air Pollution

(power plant)

local

high

high

sufficient

Sulphur dioxide

2

Pollution of Inland Waterways

local

low

low

sufficient

Insecticides: Organochlorine

Herbicides, Fungicides

Heavy metals

3

Marine Pollution

local

high

medium

sufficient

Heavy metals (mercury, lead, cadmium, chromium, copper, nickel, manganese, zinc), total organochlorine pesticides (DDT, alpha-BHC, dieldrin, aldrin, endrin, heptachlor & heptachlor epoxide)

3

Groundwater Pollution

local

medium

low

insufficient

Chlorinated compounds (heptachlor, dieldrin, aldrin, BHC, DDT, endosulfan ) atrazine, carbofuran, 2,4 ?D, heavy metals ( mercury, cadmium, lead, arsenic )

3

Soil Contamination

national

low

low

insufficient

Heavy metals (cadmium, zinc, lead, manganese)

3

Shallow-well water Pollution

local

low

low

insufficient

Organochlorine insecticides:

- dieldrin

- DDT derivatives

- dicofol

- endosulfan

- beta-BHC

Organophosphoropus insecticides:

- parathion-methyl

3

Unknown Chemical Imports

-

-

-

insufficient

-

-

Hazardous Waste Treatment /Disposal

national

medium

low

insufficient

Hazardous waste

2

Occupational Health:

Agricultural

regional

medium

medium

sufficient

pesticides

3

Occupational Health:

Industrial

regional

medium

medium

insufficient

Lead, manganese, mercury arsenic, petroleum products and volatile gases

3

Chemical Accidents: Industrial

regional

medium

medium

insufficient

Chlorine gas, ammonia gas

3

Chemical Accidents:

Transport

local

medium

low

insufficient

LPG (Liquid Petroleum Gas), vinyl chloride, trinitrotoluene (TNT)

2

Storage / Disposal of Obsolete Chemicals

national

medium

low

insufficient

Methyl bromide, oxidizing agents, pesticides, carbon black, benzene, acrylonitrile, Butadiene-Styrene (ABS)

3

Persistant Organic Pollutants

regional

medium

medium

Sufficient only on pesticides

12 POPs

3

Chemical Residues in Food

national

medium

medium

insufficient

Metals

Organophosphorous

pesticides

Veterinary drugs

Other chemicals

2

Drinking Water Contamination

local

low

medium

insufficient

Arsenic

3

Public Health

local

low

medium

sufficient

DDT

3

Chemical Poisoning / Suicides

local

low

medium

sufficient

Pesticides, Herbicides, Sedatives / hypnotics, Rodenticides

4

 

1. Scale of Problem = Local, regional or national

2. Level of Concern , Ability to Control Problem = Low, medium or high

3. Availability of Statistical Data = Sufficient, insufficient or no data available

4. Priority Ranking = 1 (most severe problem), 2 (second most severe problem), and on to the scale of 4 ( least severe problem ). F: ch3.doc